Starch is the stored form of sugars in plants. It is made up of a mixture of amylose andamylopectin, both polymers of glucose.

Plants synthesizeglucosethrough photosynthesis. The excess glucose, beyond the plant’s immediate energy needs, is stored as starch in areas including the roots and seeds. The starch in the seeds provides food for the plant embryo as it germinates, and is also a source of food for humans and other animals.

Animals that consume starch must break it down into digestible sugars using enzymes, such as salivaryamylases. Such enzymes break apart the polysaccharide chain into simpler sugars such asmaltoseandglucose. The cells can then absorb the glucose.

Starch is made up of glucose monomers that are joined by α 1,4 or α 1,6glycosidic bonds. The numbers 1,4 and 1,6 refer to the carbon number of the two residues that have joined to form the bond. Because of the way the subunits are joined, the glucose chains have a helical structure.

Amylose is a glucose polymer. At the top of the image is a chain of circles joined together to show the unbranched polymer chain. Below that is the structure of glucose polymer, which shows how the glucose monomers can join together using 1, 4, glycosidic bonds. The 6-membered ring form of glucose is made of carbons 1 to 5, with oxygen between carbon 1 and carbon 5. The O H groups at carbons 2 and 4 point down. The O H group at carbon 3, and the C H 2 O H group at carbon 5, point up.

Figure 1:直链淀粉是由联合国组成的branched chains of glucose monomers connected by α 1,4 glycosidic linkages.


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